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PH標(biāo)準(zhǔn)緩沖溶液與溫度的關(guān)系

發(fā)布日期: 2022-06-01
瀏覽人氣: 4081

常用的標(biāo)準(zhǔn)pH緩沖溶液及溫度和緩沖溶液的關(guān)系

國內(nèi)常用的標(biāo)準(zhǔn) pH 緩沖溶液為標(biāo)稱 pH4 , pH7 和 pH9.18 的三種,它們的成分是;

pH4:0.05M 鄰苯二甲酸氫鉀溶液

pH7:0.025M 磷酸二氫鉀和磷酸氫二鈉混合鹽溶液

pH9:0.01M 硼砂溶液


溫度(℃)

0

5

10

15

20

25

30

35

40

45

50

55

60

70

80

90

95

PH4

4.01

4.00

4.00

4.00

4.00

4.00

4.01

4.02

4.04

4.04

4.06

4.04

4.09

4.12

4.16

4.20

4.22

PH7

6.98

6.95

6.92

6.90

6.88

6.86

6.85

6.84

6.84

6.83

6.83

6.83

6.84

6.85

6.86

6.88

6.89

PH9

9.46

9.38

9.33

9.28

9.23

9.18

9.14

9.10

9.07

9.04

9.02

8.99

8.97

8.93

8.89

8.86

8.84


可以把標(biāo)準(zhǔn)緩沖液 pH 值與溫度 關(guān)系擬合成溫度 的三次函數(shù) ;

pH(t) =[a b c d] =a*t^3+b*t^2+c*t+d

pH4(t)=[-2.4466e-007 6.3878e-005 -1.6467e-003 4.0090];

pH7(t)=[-3.5620e-007 9.6662e-005 -6.9343e-003 6.9811];

pH9(t)=[-5.2120e-007 1.2823e-004 -1.3994e-002 9.4592];

2.gif 

pH4 標(biāo)準(zhǔn)緩沖液 pH 值與溫度關(guān)系曲線 擬合曲線與數(shù)據(jù)點 )

3.gif

pH7 標(biāo)準(zhǔn)緩沖液 pH 值與溫度關(guān)系曲線 ( 擬合曲線與數(shù)據(jù)點 )

4.gif

pH9 標(biāo)準(zhǔn)緩沖液 pH 值與溫度關(guān)系曲線 ( 擬合曲線與數(shù)據(jù)點 )


       上海闊思是您水處理領(lǐng)域小伙伴!


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